2015-3-1 · The ball milling process was carried out in a Fritsch Pulverisette 6 planetary mono mill. The olivine basalt was subjected to wet milling in an 80 mL tungsten carbide bowl using deionized H 2 O or ethanol as process control agent (PCA). The ball-to-powder mass ratio was 20:1 w/w, the fluid-to-powder mass ratio 1:10 or 1:2 and the rotation speed 300 rpm.
2016-12-1 · In this study, the influence of high energy ball milling and supercritical carbon dioxide impregnation on the properties of binary systems, composed of TD and SL, were compared. For all the formulations, TD was vitrified by high energy ball milling, while it was found to remain crystalline after the scCO 2 impregnation process. In the latter ...
In this study, two methods, i.e. high energy ball-milling and supercritical carbon dioxide impregnation (scCO 2) are compared, with the aim to predict their suitability for the vitrification of TD. The influence of the amount of SL and the kind of co-processing method on TD thermal properties is analyzed.
The positive effect of H2O on CO2 chemisorption becomes much more evident after the ball milling process. Specifically, the CO2 uptake of the ball
Mineral carbonation is considered to be the most stable mechanism for the sequestration of CO2. This study comprises a comparative review of the effect of ball milling on the CO2 uptake of ultramafic/mafic lithologies, which are the most promising rocks for the mineralization of CO2. Samples of dunite, pyroxenite, olivine basalt and of a dolerite quarry waste material were
2016-11-2 · Carbon dioxide absorption behavior of surface-modified lithium orthosilicate/potassium carbonate prepared by ball milling. Author links open overlay panel Kyohei Kanki a Hideshi Maki a b Minoru Mizuhata a. ... Ball-milling time dependences of the ESR spectra of (a) Li 4 SiO 4 and (b) Li/K 5.
Ball-milling synthesis of Co 2 P nanoparticles encapsulated in nitrogen doped hollow carbon rods as efficient electrocatalysts† Haitao Wang , a Wei Wang , a Yang Yang Xu , a Muhammad Asif , a Hongfang Liu * a and Bao Yu Xia * ab
2018-6-13 · REVIEW PAPER Capture of CO2 on γ-Al2O3 materials prepared by solution-combustion and ball-milling processes F. Granados-Correa a, J. Bonifacio-Martínez , H. Hernández-Mendozaa, and S. Bulbulianb aDepartamento de Química, Instituto Nacional de Investigaciones Nucleares, México D.F., México; bCentro de Ciencias Aplicadas y Desarrollo
2019-5-1 · Carbon dioxide capture/release reactions using magnetite, Fe 3 O 4, and hematite, Fe 2 O 3, as sorbents were studied.Kinetics of mechanically activated chemical reactions between iron oxides and CO 2 was investigated as a function of CO 2 pressure and planetary ball mill process parameters. It was found that complete carbonation of iron oxides can be
2021-11-18 · In this context, the use of ball milling techniques 16,17,18,19,20,21,22,23,24 for the solvent-free preparation of Grignard reagents via reactions between aryl halides and magnesium metal has been ...
The positive effect of H2O on CO2 chemisorption becomes much more evident after the ball milling process. Specifically, the CO2 uptake of the ball
2016-12-1 · In this study, two methods, i.e. high energy ball-milling and supercritical carbon dioxide impregnation (scCO2) are compared, with the aim to predict their suitability for the vitrification of TD. The influence of the amount of SL and the kind of co-processing method on TD thermal properties is analyzed.
2019-3-7 · geosciences Communication Ball Milling Effect on the CO2 Uptake of Mafic and Ultramafic Rocks: A Review Ioannis Rigopoulos 1,2,*, Ioannis Ioannou 2, Andreas Delimitis 3, Angelos M. Efstathiou 4 and Theodora Kyratsi 1 1 Department of Mechanical and Manufacturing Engineering, University of Cyprus, 1678 Nicosia, Cyprus; [email protected] 2 Department of
Figure 8. 2 te erat re- ro ra e esor tio ( ) traces o tai e er e flo for the un illed dunite (S 15) and the ball- illed rock aterial ith the highest C 2 uptake (B 45). Adsorption conditions: 5 vol CO2/He (50 N mL/min) at 500 C for 30 min followed by cooling of the sample to 50 C under the same gas mixture. Desorption conditions: QHe = 50 N mL/min, = 30 C/min (data from Rigopoulos et al.
2016-11-2 · Carbon dioxide absorption behavior of surface-modified lithium orthosilicate/potassium carbonate prepared by ball milling. Author links open overlay panel Kyohei Kanki a Hideshi Maki a b Minoru Mizuhata a. ... Ball-milling time dependences of the ESR spectra of (a) Li 4 SiO 4 and (b) Li/K 5.
Carbon dioxide absorption behavior of surface-modified lithium orthosilicate/potassium carbonate prepared by ball milling ... bulk diffusion at temperatures above 773 K. Isothermal analysis indicated that ball milling and adding K2CO3 decreased the activation ...
2021-12-23 · A one-pot three-step protocol for the preparation of Grignard reagents from organobromides in a ball mill and their subsequent reactions with gaseous carbon dioxide (CO 2 ) or sodium methyl carbonate providing aryl and alkyl carboxylic acids in
Edge-selectively functionalized graphene nanoplatelets (EFGnPs) with different functional groups were efficiently prepared simply by dry ball milling graphite in the presence of hydrogen, carbon dioxide, sulfur trioxide, or carbon dioxide/sulfur trioxide mixture. Upon exposure to
2021-11-18 · In this context, the use of ball milling techniques 16,17,18,19,20,21,22,23,24 for the solvent-free preparation of Grignard reagents via reactions between aryl halides and magnesium metal has been ...
2021-8-27 · Grignard reactions invert the intrinsic electrophilic reactivity of organohalides to form C–C bonds with other electrophiles. With carbon dioxide (CO2) as electrophile carboxylic acids can be prepared. Although scattered examples of mechanochemical reactions with CO2 have been reported, its synthetic application as C1-synthon has remained underexplored. Here, we
2016-12-1 · In this study, two methods, i.e. high energy ball-milling and supercritical carbon dioxide impregnation (scCO2) are compared, with the aim to predict their suitability for the vitrification of TD. The influence of the amount of SL and the kind of co-processing method on TD thermal properties is analyzed.
2019-3-7 · geosciences Communication Ball Milling Effect on the CO2 Uptake of Mafic and Ultramafic Rocks: A Review Ioannis Rigopoulos 1,2,*, Ioannis Ioannou 2, Andreas Delimitis 3, Angelos M. Efstathiou 4 and Theodora Kyratsi 1 1 Department of Mechanical and Manufacturing Engineering, University of Cyprus, 1678 Nicosia, Cyprus; [email protected] 2 Department of
2018-11-7 · Adsorbed CO2 (μmol g −1 ) versus ball milling time (h) for the unmilled and ball-milled dunite, pyroxenite, basalt and dolerite samples (data from Rigopoulos et al. [19,25,32,33]).
Mineral carbonation is considered to be the most stable mechanism for the sequestration of CO2. This study comprises a comparative review of the effect of ball milling on the CO2 uptake of ultramafic/mafic lithologies, which are the most promising rocks for the mineralization of CO2. Samples of dunite, pyroxenite, olivine basalt and of a dolerite quarry waste material were
Figure 8. 2 te erat re- ro ra e esor tio ( ) traces o tai e er e flo for the un illed dunite (S 15) and the ball- illed rock aterial ith the highest C 2 uptake (B 45). Adsorption conditions: 5 vol CO2/He (50 N mL/min) at 500 C for 30 min followed by cooling of the sample to 50 C under the same gas mixture. Desorption conditions: QHe = 50 N mL/min, = 30 C/min (data from Rigopoulos et al.
Ball-milling synthesis of Co 2 P nanoparticles encapsulated in nitrogen doped hollow carbon rods as efficient electrocatalysts† Haitao Wang , a Wei Wang , a Yang Yang Xu , a Muhammad Asif , a Hongfang Liu * a and Bao Yu Xia * ab
2016-4-18 · Mechanical activation is an effective method for destroying the crystalline structure. Biomass, especially its hemicellulose, can be degraded in the green solvent of liquid hot-water compressed carbon dioxide. To improve the degradation of crystalline cellulose in liquid hot-water compressed carbon dioxide, pretreatment of camphorwood sawdust by mechanical activation
2021-12-23 · A one-pot three-step protocol for the preparation of Grignard reagents from organobromides in a ball mill and their subsequent reactions with gaseous carbon dioxide (CO 2 ) or sodium methyl carbonate providing aryl and alkyl carboxylic acids in
2021-11-18 · In this context, the use of ball milling techniques 16,17,18,19,20,21,22,23,24 for the solvent-free preparation of Grignard reagents via reactions between aryl halides and magnesium metal has been ...
2019-2-26 · Negative carbon emission technologies are critical for ensuring a future stable climate. However, the gaseous state of CO2 does render the indefinite storage of this greenhouse gas challenging.